10 ENGLISH BOOKS RELATING TO «ACETYLIDE»
Discover the use of
acetylide in the following bibliographical selection. Books relating to
acetylide and brief extracts from same to provide context of its use in English literature.
7-5 Preparation of Alkynes A. Alkylation of Acetylide Anions with Methyl and 1°
Haloalkanes As we have already seen, an acetylide anion is a strong base. An
acetylide anion is also a nucleophile; it has an unshared pair of electrons that it
can ...
William Brown, Brent Iverson, Eric Anslyn, 2013
2
A Comprehensive Guide to the Hazardous Properties of ...
30.2 CUPROUS ACETYLIDE Formula Cu2C2; MW 151.11; CAS [1117- 94-8]
Structure and reactivity: C CuCÁC C Cu, copper salt of weakly acidic acetylene,
strong nucleophile Synonyms: cuprous carbide; copper(I) ace- tylide Uses and ...
3
Hazardous Chemicals Handbook
... acetylides Disilver acetylide Silver acetylide-silver nitrate Digold(I) acetylide
Barium acetylide Calcium acetylide (carbide) Dicaesium acetylide Copper(II)
acetylide Dicopper(I) acetylide Silver acetylide Caesium acetylide Potassium
acetylide ...
4
Synthesis: Carbon with No Attached Heteroatoms
Acetylide anions do not require the presence of electron-withdrawing groups for
stabilisation, the carbanion being stabilised sufficiently as a result of the high 5
character of the carbon atom. Addition of acetylide anions to electrophilic centres
...
K. Meth-Cohn, Ree, Stanley M. Roberts, 2003
5
Organic Chemistry, Enhanced Edition
The presence of a negative charge and an unshared electron pair on carbon
makes acetylide anions strongly nucleophilic. As a result, they react with many
different kinds of electrophiles. Problem 8.9 The pKa of acetone, CH3COCH3, is
19.3.
6
Bretherick's Handbook of Reactive Chemical Hazards: 2-Volume Set
Dicopper(I) acetylide, 0616 Dimethyl-1-propynylthallium, 1932 Dimethyl(
phenylethynyl)thallium, 3292 Gold(I) acetylide, 0570 Lithium 1-heptynide, 2830 *
Lithium 3-(1,1,2,2-tetrafluoroethoxy)propynide, 1814 Lithium acetylide, 0988
Lithium ...
7
Organolithiums in Enantioselective Synthesis
A model for the rather unreactive species, which is formed after 50% conversion,
is given by the 3:1 tetramer 29, which forms, according to NMR investigations,
from three equivalents of alkoxide 26 and one equivalent of acetylide 25 [88].
8
Heteronuclear Metal-Metal Bonds
3.4.3 Acetylide Clusters and their Derivatives 3.4.3.1 Trinuclear acetylide clusters
Attention has focused on the reactivity of carbonyl clusters with acetylide ligands.
Treatment of [CpM(CO),«:R)] (M = Mo, R = Me; M = W, R = Me or Tol) with the ...
Edward W. Abel, Richard D. Adams, Francis Gordon Albert Stone, 1995
9
Molecular Organometallic Materials for Optics
As expected, the quadratic hyperpolarizability [11, 19, 144–147] increases upon
increasing the chain length of the acetylide bridge (e.g., 36 vs 37, b1.06(HRS) =
351 × 10−30 esu; b0(HRS) = 55 × 10−30 esu, for the latter) [145], and increasing
...
Hubert Bozec, Véronique Guerchais, 2009
10
Platinum Terpyridine
Acetylide Complexes for Photo-induced ...
Chapter 2 describes a continuation of previous efforts to make molecular triads which employ pyridinium acceptors, including the viologen moiety.
5 NEWS ITEMS WHICH INCLUDE THE TERM «ACETYLIDE»
Find out what the national and international press are talking about and how the term
acetylide is used in the context of the following news items.
Copper click chemistry mechanism unravelled
However, their isolation of a previously postulated π,σ-bis(copper) acetylide and a bis(metallated) triazole complex that has never been ... «Royal Society of Chemistry, Jun 15»
Inventive technique transforms a common reagent into a …
Under certain conditions, the team noticed that small amounts of enaminones were also produced—a finding that suggested liquid acetylide ... «Phys.Org, Nov 13»
ATF List of Explosives Materials
Copper acetylide. Cyanuric triazide. Cyclonite [RDX]. Cyclotetramethylenetetranitramine [HMX]. Cyclotol. Cyclotrimethylenetrinitramine [RDX]. «Cryptome.org, Oct 13»
US presses Pakistan on bomb fertiliser
Copper(I) acetylide. Copper(II) azide. Cumene hydroperoxide. Cyanogen azide. Diacetyl peroxide. Diazodinitrophenol Diazomethane «The Express Tribune, Dec 12»
CHEMICAL DATA NOTEBOOK SERIES #104: PROPYLENE OXIDE
Propylene oxide is slightly corrosive and may react violently on contact with acetylide-forming metals such as copper and its alloys. NONFIRE ... «FireEngineering.com, Aug 11»
