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1
Basic Principles in Nucleic Acid Chemistry - Volume 2 - Page 401
In comparison of these dififerent spectra, that of (Ip)2I in high salt is practically identical to that of IpI in low salt, except a slight blue shift of the CD band from 252 to 248 run; while the intensity of the CD band at 248 nm of the (Ip)2I in low salt is ...
2
Photosynthesis: Mechanisms and Effects: Volume I ... - Page 320
results indicate that there is a positive linear correlation between the negative red CD band and gem-factor. Because the negative CD band is expected to originate from chiral macrodomains at certain locations in chloroplasts [9], the result ...
3
Conformation in Biology and Drug Design: The Peptides: ...
The CD band may be either positive or negative. However, since for a given transition in a given enantiomer either lcp or rcp may be absorbed more strongly, the other enantiomer will have a CD band of equal magnitude but opposite sign for ...
Sidney Udenfriend, Johannes Meienhofer, Victor J. Hruby, 2014
4
DNA - Recombination Interactions and Repair: Proceedings ...
In the range of doses < 6 x 10 J.m " we observed a monotonous growth of the positive CD band, corresponding to DNA, and a deepening of the negative band of proteins (Fig. 1) (Worlíčková, Paleček, Sponar, 1979). Sedimentation ana“AA, 10.
S. Zadrazil, J. Sponar, 2014
5
A Laboratory Manual of Analytical Methods of Protein Chemistry
correction into his derivation (Eq. (36a)); thus, for the ORD of each CD band Eq. (36b) differs from Eq. (23b) by a factor of (n” +2)/3. By expanding Eq. (35) into a Taylor's series in terms of (A*- A')" (A. is a parameter to be determined), we have ...
P. Alexander, H. P. Lundgren, 2014
6
Chromatin and Chromosome Structure - Page 97
The effect of H2A is to greatly augment the positive CD band of DNA, in a manner similar to that of H4 and H2B. The arginine—rich histone H3 contains 135 residues, has a typical amino acid distribution with many basic residues clustered in ...
7
Peptides: Frontiers of Peptide Science - Page 163
Based on its negative CD band at 310 nm, the braced tripod exists predominantly in the conformation [4]. In 20:1 (v/v) acetonitrile/water, the proline-II helical form of the unbraced tripod undergoes substantial isomerization into the proline-I ...
James P. Tam, Pravin T.P. Kaumaya, 2006
8
Molecular Mechanisms Of Oxygen Activation - Page 146
When the enzyme is titrated by substrate under anaerobic conditions, 3 moles of catechol per mole of enzyme are required to bring about maximal change of the CD band at 317 nm, suggesting that 3 moles of catechol can combine with 1 ...
9
Bulletin of the Chemical Society of Japan
monstrated with regard to [PdCh(S-pn)] that the main negative CD band in the spin-allowed d-d region was primarily based on the 'Ej^-'Ai, transition, although it included a minor contribution by the 'Big*— 1Ai, transition (D<h).a This situation ...
10
Molecular Gels: Materials with Self-Assembled Fibrillar ... - Page 110
222nm in spectra for c < 50μM is characteristic of random coil monomeric peptide, whereas the negative CD band at ca. 214 nm and the positive band below ca. 195 nm, at 150μM< ca. < 400μM is typical of a β-sheet conformation [16].
Richard G. Weiss, Pierre Terech, 2006
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