10 BÜCHER, DIE MIT «BENZYLIC» IM ZUSAMMENHANG STEHEN
Entdecke den Gebrauch von
benzylic in der folgenden bibliographischen Auswahl. Bücher, die mit
benzylic im Zusammenhang stehen und kurze Auszüge derselben, um seinen Gebrauch in der Literatur kontextbezogen darzustellen.
1
Organic Chemistry the Easy Way
H. Free-Radical. Halogenation. of. Allylic. and. Benzylic. Hydrogens. Here are
another couple of organic chemistry jargon terms you need to know. An allylic
carbon refers to the carbon next to a C=C. The hydrogens on an allylic carbon
are ...
0 Several characteristic reactions occur at the benzylic position of aromatic hydro
— carbons because benzylic cation and radical intermediates are stabilized
through delocalization into the aromatic ring. 0 Compounds with at least one ...
William Brown, Brent Iverson, Eric Anslyn, 2013
3
Science of Synthesis: Houben-Weyl Methods of Molecular ...
Benzyl hydroperoxide, 4-methyl-, from photolytic autoxidation of p-xylene 114,
115 Benzylic alcohols, from reduction of benzylic peroxides, using
diisobutylaluminum hydride 265 Benzylic alcohols, perhydrolysis, using
hydrogen peroxide, acid ...
Wilhelm J. Baader, Erick Leite Bastos, Daniel Bellus, 2014
4
Science of Synthesis: Houben-Weyl Methods of Molecular ...
... 336 Benzyl chlorides – see also Benzylic chlorides fi Benzyl chlorides, 2-chloro
-, from reaction of 2-chlorotoluene with sulfuryl chloride–dibenzoyl peroxide 144,
146 fi Benzyl chlorides, from chlorination of toluene, using phosphorus ...
Daniel Bellus, Manfred Braun, Tonia Freysoldt, 2014
5
Transition Metal Reagents and Catalysts: Innovations in ...
The negative charge on the benzylic position of the side chain is stabilized by the
electron-withdrawing effect of coordinated Cr(CO)3. In complex 234, attack of a
carbanion occurs at the /^-carbon of the double bond to generate the stabilized ...
6
Drug Metabolism: Chemical and Enzymatic Aspects
Oxidation of Benzylic and Allylic sp3 Carbon–Hydrogen Bonds Benzylicandallylic
carbon–hydrogen bondhydroxylationwouldbe expected tobe energetically
favored processes if they proceed by the same P450-catalyzed hydrogen
abstraction ...
Jack P. Uetrecht, William Trager, 2007
7
Advanced Organic Chemistry: Reactions And Mechanisms
But what about benzylic, allylic. vinylic and aryl halides? Let us first consider
benzylic and allylic halides. Benzylic and allylic halides readily undergo ^2
reactions unless they are tertiary. Tertiary benzylic and allylic halides, like other
tertiary ...
8
Science of Synthesis: Houben-Weyl Methods of Molecular ...
... of 3-hydroxybenzoic acid, using boranes, trimethyl borate accelerated 61 fi
Benzylic alcohols, chiral, from asymmetric hydroxylation of arylethanes, using 2,6
-dichloropyridine N-oxide, ruthenium porphyrin catalyzed 576 fi Benzylic alcohols
, ...
Daniel Bellus, Richard Brown, Jonathan Clayden, 2014
9
Journal - Chemical Society, London
benzylic alcohol may thereforo be represented by the following equation : — 2C,
H60 + CNCl = CO | JJJ^ + C,H7C1. Benzylic Cyanogen Benzylic Benzylic alcohol
. chloride. carbamate, chloride. The same products are obtained with solid ...
Chemical Society (Great Britain), 1871
10
Organic Chemistry, Enhanced Edition
Benzyl group Reactions involving alkyl side chains of aromatic compounds occur
preferentially at the benzylic position for two reasons. First, the benzene ring is
especially resistant to reaction with many of the reagents that normally attack ...
William Brown, Christopher Foote, Brent Iverson, 2010
10 NACHRICHTEN, IN DENEN DER BEGRIFF «BENZYLIC» VORKOMMT
Erfahre, worüber man in den einheimischen und internationalen Medien spricht und wie der Begriff
benzylic im Kontext der folgenden Nachrichten gebraucht wird.
Synthesis and characterization of an important intermediate for …
They found that APO-II has a surprisingly high reactivity toward phenols and substrates with relatively weak benzylic carbon-hydrogen bonds. «Phys.Org, Mär 15»
Fluorination Remains Key Challenge in API Synthesis
... synthesis of monofluorinated benzylic substrates (2), the silver-catalyzed decarboxylative fluorination of aliphatic carboxylic acids (3), and the chemoselective, ... «Pharmaceutical Technology Magazine, Okt 14»
Privileged strategies for direct transformations of inert aliphatic …
Some progress has also been made in achieving the direct transformation of relatively active benzylic and allylic C–H bonds. In contrast, less ... «Science Codex, Jul 14»
Chemists make headway on C–H activation challenges
Yu's team sought to direct palladium-mediated catalytic attack on the meta-C–H bonds of bicyclic anilines and benzylic amines. This was done ... «Chemistry World, Mär 14»
Senteurs du Sud Beurre d'Argan / Argan Butter (2013): An Excellent …
... olive esters, Squalane, Caprylic capric triglycerides, Sodium benzoate, Potassium sorbate, Benzylic alcohol, Tocopherol, Sodium borate. «Mimi Froufrou, Jun 13»
Column: Totally Synthetic
... blue light and a ruthenium bipyridyl catalyst. This generates a tertiary benzylic radical, just stable enough to be reactive but not prone to degradation (figure 1). «Chemistry World, Sep 11»
Ligand could trap actinides from spent nuclear fuel
... the structure into a rigid horseshoe shape, and replaced vulnerable benzylic hydrogens with more stable tetramethylcyclohexyl groups. «Chemistry World, Aug 11»
One dimensional carbon chains get longer
'This choice, which entails a triple benzylic system, is not so obvious because of the thermodynamically weaker terminal sp3-sp carbon bond ... «Chemistry World, Sep 10»
Peer review by live blogging
... described how the authors were attempting the standard preparation of the sodium alkoxide salt of a benzylic alcohol using sodium hydride. «Chemistry World, Jul 09»
Total synthesis of marine natural products without using protecting …
To accomplish the conversion of 18 to 5, an oxidant was chosen that was more suited to benzylic oxidations. By simply exposing 18 to DDQ in ... «Nature.com, Mär 07»
