ETYMOLOGY OF THE WORD SCHIFF BASE
Named after Hugo Schiff (1834–1915), German chemist.
10 ENGLISH BOOKS RELATING TO «SCHIFF BASE»
Discover the use of
Schiff base in the following bibliographical selection. Books relating to
Schiff base and brief extracts from same to provide context of its use in English literature.
1
Preparation of Chiral Acid-functionalized
Schiff-
base ...
Acid-functionalized Schiff-base ligands with a thiol as the fourth donor ... Cubane
structures of the two Schiff-base ligands sae2- and sap2-. ...............14 Figure 1.15.
... Complexation of BINAM based Schiff-base ligands; the effect of solvent.
2
New [3+3]
Schiff-
base Macrocycles and Their Complexes
Upon addition of small cations, the conjugated Schiff-base macrocycles assemble into tubular structures.
Amanda Jane Gallant, 2007
3
Synthetic Efforts Toward Fumonisin Via Amino Acid
Schiff ...
Synthetic efforts toward fumonisin analog were described. These are accomplished via amino acid Schiff base methodology. These efforts can be divided three major phases.
1t was converted to a schiff base with salicylaldehyde, which was isolated in pure
form, dried and weighed 1ts melting point was determined. The general structure
assigned is supported by their IR. spectral bands. Key words: Cephalexin ...
5
Chemsitry and Biology of Synthetic Retinoids
reduction of the pKa of the protonated Schiff base as a consequence of light
absorption. Thus, understanding the factors influencing the pKa of model RSBH+
is a prerequisite for clarifying the retinal-opsin interactions that affect the pKa of
the ...
Marcia I. Dawson, William H. Okamura, 1990
6
Light Sensing in Plants
The rhodopsin structure controls retinal Schiff-base hydrolysis, retinal release
and MII decay. The retinal Schiff-base linkage is dramatically stabilized in the
dark-state rhodopsin (the t1/2 for hydrolysis is days). In contrast, in MII rhodopsin,
the ...
M. Wada, K. Shimazaki, M. Iino, 2007
7
Hydrogen Bonding and Transfer in the Excited State
It is believed that the interaction between the protonated Schiff base and Cl −
plays a crucial role in the vectorial transport of the chloride ion. Therefore, it is
essential experimentally to monitor the hydrogen-bonding strength of the Schiff
base ...
Ke-Li Han, Guang-Jiu Zhao, 2011
It was converted to a schiff base with salicylaldehyde, which was isolated in pure
form, dried and weighed. Its melting point was determined. The general structure
assigned is supported by their IR. spectral bands. Key words: Cephalexin, Schiff
...
9
Bioconjugate Techniques
Carbonyl groups such as aldehydes, ketones, and glyoxals can react with
amines to form Schiff base intermediates which are in equilibrium with their free
forms. The interaction is pH dependent, being more efficient at low pH and
especially ...
10
Molecular Mechanisms in Bioenergetics
Small motions, involving a few amino acids or a slight helix tilt, were observed
near the Schiff base and the /3-ionone ring of retinal. Small differences between
bR and M were also observed by electron cryomicroscopy at 3.3 A resolution [
198] ...
3 NEWS ITEMS WHICH INCLUDE THE TERM «SCHIFF BASE»
Find out what the national and international press are talking about and how the term
Schiff base is used in the context of the following news items.
Magnetic field and pH synergy controls therapeutic burst
... where a magnetite (Fe3O4) nanoparticle is bound to a temperature-responsive polymer onto which drug molecules can be attached via Schiff base bonds. «Chemistry World, Mar 14»
Switching chirality in amino acids
A Ni(II) amino acid Schiff base complex with three stereogenic centres, including a stereogenic nitrogen, was formed under mild and operationally simple ... «Chemistry World, Jun 13»
Grabbing “X-ray snapshots” of chemical reactions
To test their idea, the authors decided to study the formation of a Schiff base, a textbook reaction that is important for many biochemical processes. During the ... «Ars Technica, Oct 09»
