«EPOXIDATION»に関連する英語の本
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1
Mechanisms in Homogeneous and Heterogeneous
Epoxidation ...
This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst ...
2
I. Mechanisms of Aryl Epoxide Hydrolysis. II. Biphasic ...
In a third investigation, we studied the epoxidation of several olefins with MCPBA in basic biphasic conditions.
D. Sharpless Asymmetric Epoxidation One of the most useful organic reactions
discovered in the last several decades is the titanium-catalyzed asymmetric
epoxidation of primary allylic alcohols developed by Professor Barry Sharpless,
then at ...
William Brown, Christopher Foote, Brent Iverson, 2011
4
Catalysis in Asymmetric Synthesis
There areseveral reviews available detailing the Sharpless asymmetric
epoxidation reaction.1,2 The first reports from the Sharpless group described the
stoichiometric use of the 'catalyst',3 however, the truly catalytic variant of the
reaction was ...
Vittorio Caprio, Jonathan Williams, 2009
5
Modern Physical Organic Chemistry
Connections Mechanisms of Asymmetric Epoxidation Reactions The epoxide
functional group is often an intermediate in organic synthesis sequences
because it can be readily opened by a variety of nucleophiles, leading to
complex ...
Eric V. Anslyn, Dennis A. Dougherty, 2006
Much of the experimental success of asymmetric epoxidation lies in exercising
proper control of equation (5).2 Both Ti(OR)4 and [Ti(tartrate)(OR)2] are active
epoxidation catalysts and since the former is achiral, any contribution by that
species ...
Barry M. Trost, Steven V. Ley, Ian Fleming, 1991
7
Name Reactions in Heterocyclic Chemistry
Initial studies on the Jacobson-Katsuki epoxidation reaction identified conjugated
cyclic and acyclic cis-disubstituted olefins as the class of olefins best suited for
the epoxidation reaction.“ Indeed a large variety of cis-disubstituted olefins have
...
8
Advanced Organic Chemistry: Part A: Structure and Mechanisms
504 CHAPTER 5 Polar Addition and Elimination Reactions The magnesium salt
of monoperoxyphthalic acid is an alternative.112 Peroxyacetic acid,
peroxybenzoic acid, and peroxytrifluoroacetic acid also are used frequently for
epoxidation.
Francis A. Carey, Richard J. Sundberg, 2007
9
Catalytic Asymmetric Conjugate Reactions
Alessandra Lattanzi 9.1 Introduction The asymmetric epoxidation of alkenes is a
fundamental process in organic synthesis, and unquestionably the most
exploited approach to synthesize epoxides [1]. Alternative useful strategies to
access ...
10
Handbook of Chiral Chemicals, Second Edition
10. Asymmetric. Epoxidation. of. Olefins. by. Chiral. Ketones. Yian. Shi.
CONTENTS 10.1 Introduction.............................................................................................
............................147 10.2 Ketone Catalysts for trans- and Trisubstituted Olefins .
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Global Markets for Oleochemical Fatty Acids
... or amination, while derivatives based on the unsaturation include isomerization, dimerization, epoxidation and hydrogenation acids. «PR Newswire, 6月 15»
Acrylamide in Food; Scientific Opinion provided by the European …
AA is extensively metabolised, mostly by conjugation with glutathione but also by epoxidation to glycidamide (GA). Formation of GA is ... «PotatoPro, 6月 15»
Nobel Prize Laureate Professor Barry Sharpless Visits WuXi AppTec …
... reactions that now bear his name: Katsuki-Sharpless epoxidation, Sharpless asymmetric dihydroxylation and Sharpless aminohydroxylation. «PR Newswire, 4月 15»
Acrylamide may increase cancer risk, says EFSA opinion
“Acrylamide is extensively metabolised, mostly by conjugation with glutathione but also by epoxidation to glycidamide (GA). Formation of GA is ... «FoodNavigator.com, 7月 14»
New Roles For Antifreeze Proteins
... New Roles For Antifreeze Proteins; DNA Array Profiles Combat Wound Bacteria · Efficient Epoxidation Catalyst Predicted · Green Boost For ... «The Biological SCENE, 6月 14»
Omega (ω)-3 inhibits blood vessel growth in age-related macular …
The cytochrome P450 (CYP) enzymes catalyze the epoxidation of these ω-3 LCPUFAs to form the eicosanoids 17,18-epoxyeicosatetraenoic ... «EurekAlert, 6月 14»
Easy Aziridines
A direct reaction analogous to epoxidation to give you an NH aziridine is pretty rare, but this seems to be the answer. It's a rhodium-catalyzed ... «Corante, 1月 14»
High-Resolution Mass Spectrometry: An Ideal Premier Analytical …
They catalyze many different reactions including hydroxylation, dealkylation, epoxidation, reduction, glucuronidation, and sulphation. «LCGC Chromatography Online, 9月 13»
Nobel laureates and their research teams at American Chemical …
... deoxypolypropionates, and others, through the development of catalytic asymmetric alkene hydrogenation, epoxidation, carboalumination, ... «EurekAlert, 9月 13»
Homogeneous catalysis for nanoscale surface designs
... carry out alkene epoxidation at precise locations on a self-assembled monolayer. Epoxides are a commonly used synthetic handle in organic ... «Chemistry World, 6月 13»
