«HETEROLYTIC»に関連する英語の本
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1
Homolytic and
Heterolytic Reactions: Problems and Solutions
Homolytic & Heterolytic Reactions - Problems & Solutions
Gennadiĭ Efremovich Zaikov, Alfonso Jiménez, 2004
Exercise 3.20 Draw the structures of the radicals that would be produced by
homolytic cleavage of each of the bonds shown in Table 3.4. In heterolytic
cleavage, the two electrons initially shared in a bond are distributed unequally —
that is, ...
Marye Anne Fox, James K. Whitesell, 2004
3
Heterolytic fragmentation of organic molecules
An examination of heterolytic fragmentation reactions aid in understanding stereoelectronic effects in organic chemistry.
4
Heterogeneous Catalysis
Chemical reactions where the formation and disruption of the electron-pair bonds
proceeds without destroying and forming electron pairs are called heterolytic.
This distinction can be applied to the interaction of the reactants with a catalyst.
Georgiĭ Konstantinovich Boreskov, 2003
Classify each as A carbocation B carbanion C free radical D none of these
CH3CH2- 3 CH, 5 "OH 2 CH3CH.CH, 4 CH3CH2" 6 -OH Which type of bond
fission, homolytic or heterolytic, would you expect for (a) a bond between
identical atoms, ...
Graham Hill, John Holman, 2000
6
Advanced Organic Chemistry: Part A: Structure and Mechanisms
However, in solution, where stabilization of the ions by solvation becomes
possible, heterolytic bond dissociation can become energetically feasible.
Heterolytic bond dissociations are even more sensitive to structural changes than
homolytic ...
Francis A. Carey, Richard J. Sundberg, 2000
7
Catalytic Oxidations with Hydrogen Peroxide as Oxidant
The principal heterolytic mechanisms involving metal-catalyzed organic substrate
oxidation by hydrogen peroxide typically proceed with fewer elementary
processes than their homolytic counterparts [1,23]. Some of these processes,
including ...
8
Introduction to Mass Spectrometry: Instrumentation, ...
A good example involves heterolytic cleavage that takes place when the charge
and the radical are associated with the carbonyl oxygen atom of a ketone (
Scheme 6-11). The actual cleavage in this case occurs at the alpha carbon.
However ...
J. Throck Watson, O. David Sparkman, 2008
9
Orbital Interaction Theory of Organic Chemistry
The dominant factor determining the heterolysis energy therefore is the difference
in orbital energies in the denominator, and one has directly the prediction (Figure
4.2) that case of heterolytic cleavage for C~X is in the order C > N > O > F. The ...
10
Organic Reaction Mechanisms: A Step by Step Approach, Second ...
This type of bond cleavage is called heterolytic fission. Draw the bond fission that
would occur in chloromethane. CH3 + Cl The most polarised bond is the C-C1
bond, with the chlorine being at the more negative end. If this bond should break,
...
Michael Edenborough, 1998
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JEE Advanced 2015: syllabus for Chemistry
... Polarity and inductive effects in alkyl halides; Reactive intermediates produced during homolytic and heterolytic bond cleavage; Formation, ... «India Today, 2月 15»
Molecule's carbon chain length affects oxygen's departure in key …
"Again this process was very different from the one we saw for alcohols as it proceeded by a hemolytic rather than heterolytic bond breaking ... «Phys.Org, 12月 13»
