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1
Thermodynamics of Chemical Systems
The excess quantity, Aufm, is a function of the molalities of all the solutes as well
as the temperature and pressure. It may alternatively be written as RT In y,,_,,,.
The quantiy )»,,,,,, is called the activity coefficient of the kth component based on
...
Scott Emerson Wood, Rubin Battino, 1990
2
The Formation and Stability of Saline Minerals at the ...
were chosen by setting mn+,i and mHso4-,i equal to mH2so4,i and mso4,i equal
to 3mi,C2(Lso4)3- These initial molalities are used for the first linear regression,
and a set of Pitzer parameters is derived. Then, equilibrium molalities are ...
Nicholas James Tosca (III.), 2007
3
Essential Readings in Light Metals, Alumina and Bauxite
Presentation of Results Figure 1 shows the agreement over a range of
temperatures and molalities between the boiling point rise of Bayer liquors and of
sodium hydroxide solutions at equal molalities for a high-temperature Bayer plant
using ...
Don Donaldson, Benny Raahauge, 2013
4
Chemical Equilibria and Kinetics in Soils
If only a single electrolyte were present in the aqueous solution to which y± refers
, then the product of molalities on the right side of Eq. 1.13 would reduce to a
power of the mean ionic molality:8 m± = (aabb)1/(a*b)mT (1.14) where mT is the
...
5
Quanta, Matter, and Change: A Molecular Approach to Physical ...
The agreement at very low molalities (less than about 1 mmol kg−1, depending
on charge type) is impressive, and provides convincing evidence in support of
the model. Nevertheless, the departures from the theoretical curves above these
...
Peter Atkins, Julio de Paula, Ronald Friedman, 2009
The name 'limiting law' is applied to eqn 5.69 because ionic solutions ofmoderate
molalities may have activity coefficients that differ from the values given by this
expression, yet all solutions are expected to conform as b → 0. Table 5.5 lists ...
Peter Atkins, Julio de Paula, 2006
7
Atkins' Physical Chemistry
The agreement at very low molalities (less than about 1 mmolkg−1, depending
on charge type) is impressive and convincing evidence in support of the model.
Nevertheless, the departures from the theoretical curves above these molalities
are ...
Peter Atkins, Julio de Paula, 2014
8
Hydrometallurgy: Fundamentals and Applications
According to the specified stoichiometry, the molar consumption of fluoride ions is
twice that of the calcium ions, so the final molalities are given as mnnca = 0.0l80
rri—ntoonsmmca mfinF = 0.0l I9 m—2121C0nsump(¢:l Using free energy ...
9
Chemical Thermodynamics at a Glance
In expressing equilibrium constants, Km/mo, in terms of molality: r each molality
concentration term is written so as to be dimensionless, by defining a standard
molality, mo: r i.e. we effectively divide the individual molalities, represented in ...
H. Donald Brooke Jenkins, 2008
10
Student Solutions Manual for Physical Chemistry
5.62 The extended Debye–Hückel law gives agreement with experiment over a
wider range of molalities (as shown here for a 1,1electrolyte), but it fails at higher
molalities. interActivity Consider the plot of log γ± against I1/2 with B = 1.50 and ...
C. A. Trapp, Peter Atkins, M. P. Cady, 2009
