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Ferrocene, a "sandwich compound". cx / \ c *CH Figure 4. Dibenzenechromium,
another "sandwich compound". C2H5 C2H5 \ / At C2h5 | C2H4 02n, \ Al C 2 H 4
C 2 H c 2n5 I More C2»a * C2HS (C2Hi)x (C,H4)y \ / Al I (C2H4) z I C2Hg Figure
5 ...
2
Organochromium compounds
Rearrangement of 242 could give the half-sandwich compound 243 by direct
attack of one phenyl group on a second phenyl group bonded to chromium (i.e.,
by reductive coupling). The half-sandwich compound 243 could disproportionate
...
3
Chemistry and Chemical Reactivity
The structure of ferrocene was quickly established by x-ray crystallography. Like
dibenzenechromium (Figure 22.23), ferrocene is a molecular “sandwich”
compound, containing an iron atom sandwiched between two planar
hydrocarbon rings ...
John Kotz, Paul Treichel, John Townsend, 2008
4
Structural Methods in Molecular Inorganic Chemistry
The cyclopentadienyl groups have local fivefold symmetry and characteristically
simple vibrational and NMR spectra. However, there are other. Is beryllocene a
sandwich compound? 415 12.6 Is beryllocene a sandwich compound?
D. W. H. Rankin, Norbert Mitzel, Carole Morrison, 2013
5
Sasol Encyclopaedia of Science and Technology
Sandstone is used as a building material. sandwich compound An
organometallic compound in which a transition element is 'sandwiched' between
two rings of atoms. In ferrocene, C5H5— Fe— C5H5, an iron atom is sandwiched
between ...
6
Transition Elements—Advances in Research and Application: ...
(5)bis(indenyl)zirconium sandwich compound and an ansa-titanocene dinitrogen
complex. The ?(9),?(5)-bis(indenyl)zirconium sandwich compound, (?(9)-C(9)H(5
)-1,3-Pr(2))(?(5)-C(9)H(5)-1,3-(i)Pr(2))Zr, served as an isolable source of ...
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e-Study Guide for: Inorganic Chemistry by Gary L. Miessler, ...
Fulvalene Grignard reagents Sandwich compound Carbonyl Bridging ligand This
compound is commercially available as a hydrate. A fulvalene is a hydrocarbon
obtained by formally crossconjugating two rings through a common exocyclic ...
Cram101 Textbook Reviews, 2013
8
The Facts on File Dictionary of Organic Chemistry
sandwich compound man reaction (or Gatterman–Sandmeyer reaction).
sandwich compound A type of complex formed between transition-metal ions and
aromatic compounds, in which the metal ion is 'sandwiched' between the rings.
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e-Study Guide for: Chemistry and Chemical Reactivity, Volume ...
Sandwich compound: In organometallic chemistry, a sandwich compound is a
chemical compound featuring a metal bound by haptic covalent bonds to two
arene ligands. The arenes have the formula C n H n , substituted derivatives (for
...
Cram101 Textbook Reviews, 2012
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Handbook on the Physics and Chemistry of Rare Earths
Half-sandwich compIexes of porphyrins 2.1. Synthesis and reactivity The first
members of this family of compounds were reported by Buchler et al. (1971). By
treating Sc(acac)3 with H2(OEP) in imidazole at 170°C, the half-sandwich
compound ...
Karl A. Gschneidner, LeRoy Eyring, G. H. Lander, 2001
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Ferrocene is also called a "sandwich compound", because it sandwiches an iron atom between two organic rings to form a highly stable compound structure. «ABC Science Online, 1月 11»
