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1
Handbook of Radical Vinyl Polymerization
"Brings together all fundamental aspects and the latest advances in free radical vinyl polymerization, including powerful new techniques such as the initiation of radical vinyl polymerization by high-energy radiation, photoirradiation, ...
Munmaya Mishra, Yusuf Yagci, 1998
2
PVC Degradation & Stabilization - 36페이지
Because of a large chain transfer constant, molecular weight of PVC is also relatively low in solution synthesis. Solution polymerization is not used on a commercial scale because isolation of polymer requires evaporation of solvent, which is ...
3
Principles of Polymerization - 306페이지
to flexible PVC. Plasticization involves blending PVC with plasticizers (e.g., diisooctyl phthalate, tritolyl phosphate, epoxidized oils). The plasticizer imparts flexibility by acting effectively as an ''internal lubricant'' between PVC chains.
4
Handbook of Vinyl Polymers: Radical Polymerization, ... - 407페이지
Common PVC grades contain 2—3 pendant chloromethyl groups and about 0.5 long branches, formed via hydrogen abstraction from the polymer, per 1000 carbon atoms [64]. Due to the heterophasic nature of PVC polymerization processes, ...
Munmaya Mishra, Yusuf Yagci, 2008
5
Handbook of Thermoplastics - 109페이지
After only about eight vinyl chloride monomer units have joined together in a growing PVC molecule, it precipitates out of ... Although polymerization processes of vinyl chloride include suspension polymerization, bulk polymerization (also ...
Olagoke Olabisi, Kolapo Adewale, 1997
6
Advances in Engineering Fluid Mechanics: Multiphase ... - 752페이지
Multiphase Reactor and Polymerization System Hydr Nicholas P Cheremisinoff. outstanding low ... TPU/PVC BLENDS Blending of TPUs with polyvinyl chloride (PVC) has been studied by a number of researchers [20—22]. The blends of ...
Nicholas P Cheremisinoff, 1996
7
The Chemistry of Radical Polymerization - 420페이지
(b) The unsaturated end groups (2, 4 and 5) may be reactive under polymerization conditions (i. e. the polymer chains can be considered as ... As with PMMA, PVC formed by anionic polymerization is much more stable than that ...
Graeme Moad, David Henry Solomon, 2006
8
Synthetic Polymers: Technology, Properties, Applications
Table 2.3 Average specific consumptions per metric ton for the production of PVC by continuous polymerization Monomer 1050kg Emulsifier 35 kg Initiator O.lkg NaOH 2 kg Na2CO3 4kg Demineralized water 2 m3 Nitrogen 5 Mm3 Vapor 5 ...
D. Feldman, A. Barbalata, 1996
9
Engineering with Rigid PVC: Processability and Applications - 22페이지
I250 I750 500 750 I000 I500 2000 80 * 70 60 50 0.20 030 0.40 050 0.60 Figure 2.2 Correlation among specific viscosity (ngp), K value (K), and polymerization degree (P) . for inherent viscosity n inn , also known as logarithmic viscosity number ...
10
Applied Plastics Engineering Handbook: Processing and ... - 64페이지
PVC is the only major commercial polymer wherein polymerization temperature controls molecular weight and molecular weight distribution. Figure 5.4 Addition of VCM to growing PVC chain. Polymerization takes place at temperatures ...
