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1
Essentials of Physical Chemistry and Pharmacy
53.2 Two-Component Systems Containing Liquid Phases with Lower and Upper
Consolute Temperatures Triethylamine and water are completely miscible below
18.5°C, but above this temperature they are partially miscible, that is, mutual ...
Hari Jeevan Arnikar, S. S. Kadam, K. N. Gujar, 1992
2
Handbook of Detergents: Properties
Phase separation occurs on cooling with the upper consolute boundary, which is
comparatively rare and has a qualitatively different form than does the lower
consolute boundary [63]. It is generally believed that the surfactant concentration
in ...
3
Nonlinear Dielectric Phenomena in Complex Liquids
Flewelling, A.C., DeFonseka, R.J., Khaleeli, N., Partee, J. and Jacobs, D.T. (1996)
Heat capacity anomaly near the lower critical consolute point oftriethylamine-
water, J. Chem. Phys., 104, 8048-8057. 8. Rebillot, P.F. and Jacobs, D.T. (1998) ...
Sylwester J. Rzoska, Vitaly P. Zhelezny, 2006
4
Halogenated Hydrocarbons: Solubility-Miscibility with Water
Systems with upper consolute point (e.g., aniline - water) 2. Systems with both
upper and lower consolute points outside the diagram (e.g., methylpyridine -
water) 3. Systems with both upper and lower consolute points inside the diagram
(e.g. ...
5
International Critical Tables of Numerical Data, Physics, ...
V 29.20 31.70 34.20 37.00 37.65 38.65 42.15 42.5 26.11 29.98 В = С, H.
Methylcyclopentane (i7) Consolute temp. = 35°C 68.78 64.96 В = С, H 1 1,
Hexan e (l 7, 26, 66) 40.20 41.64 50.14 ...
National Research Council (U.S.), Clarence Jay West, 1926
6
Diffusion: Mass Transfer in Fluid Systems
0 ( ) As a result, x1 I x2 I 0.5 and 60 I 2kBTC, where T C is the consolute
temperature. Thus, we find that at the consolute composition, X1 6,111 » 0 in 'Y1
4X1X2TC i TC —__ _ _1__ __ kBT0x1 a 1n X1 T T (63 7) Combining this with Eq.
6.2-4 ...
7
Instant Notes in Physical Chemistry
These are known as the upper consolute temperature and the upper consolute
composition respectively. T uc is the temperature above which only one phase is
present, as liquids A and B are completely miscible at all compositions. In
contrast ...
Gavin Whittaker, Andy Mount, Matthew Heal, 2004
There are a few mixtures, such as water and nicotine, that have both an upper
and a lower consolute point, so that the boundary of the tie-line region is a closed
curve. Below the lower consolute point at 61.5◦C water and nicotine mix in all ...
9
Advanced Pharmaceutics: Physicochemical Principles
208°C two phase lower consolute temp. = 60.8°C 0.0 0.2 0.4 0.6 0.8 Nicotine in
Water (wt fraction) T e m p e r a t u r e , ° C 1.0 0 50 100 150 200 FIGURE 3.12
The partial miscibility of nicotine−water. [Graph reconstructed from data by A.
Martin ...
10
Handbook of Fluorous Chemistry
As would be intuitively expected, consolute temperatures are usually found for ca
. 50:50 (mol/mol) mixtures. Representative consolute temperatures are given in
Table 3-4. However, as is evident from the full phase diagrams, solvents can ...
John A. Gladysz, Dennis P. Curran, Istvan T. Horvath, 2006
WIADOMOŚCI, KTÓRE ZAWIERAJĄ SŁOWO «CONSOLUTE»
Sprawdź, o czym dyskutuje się w prasie krajowej i zagranicznej oraz jak jest stosowane słowo
consolute w wiadomościach.
Panayioutou passport takes centre stage
He says that the passport was issued in 2013 and not 2015 as contended by the state and that it was in the possession of the Cyprus Consolute ... «Independent Online, Maj 15»