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1
Oxidation and Antioxidants in Organic Chemistry and Biology
4.1.2 TRIMOLECULAR REACTION OF HYDROCARBON WITH DIOXYGEN In
addition to the bimolecular reactions of organic compounds with dioxygen, free
radicals are generated in an oxidized substrate in the liquid phase by the ...
Evgeny T. Denisov, Igor B. Afanas'ev, 2005
2
Handbook of Free Radical Initiators
10.3 TRIMOLECULAR REACTION OF RADICAL INITIATION BY DIOXYGEN In
addition to bimolecular reactions of organic compounds with dioxygen, free
radicals are generated in an oxidized substrate in the liquid phase by a
trimolecular ...
E. T. Denisov, T. G. Denisova, T. S. Pokidova, 2005
3
Enzymes and Coenzymes: Advances in Research and Application: ...
New research, 'A model for single-substrate trimolecular enzymatic kinetics,' is
the subject of a report. According to recent research published in the Biophysical
Journal, “We developed a kinetic model for a single-substrate trimolecular ...
is of the form ± K/d " , the result is75 IK* i Both (4.75) and (4.77) indicate that the
collision number is proportional to three concentration factors, and therefore
trimolecular reactions are expected to be third order. The rate of disappearance
of A ...
5
Combustion: Physical and Chemical Fundamentals, Modeling and ...
This preexponential factor has different meanings in uni-, bi- and trimolecular
reactions: For unimolecular reactions, the reciprocal value of A corresponds to a
mean lifetime of an activated (reactive) molecule. In dissociation reactions, this ...
J. Warnatz, Ulrich Maas, Robert W. Dibble, 2006
6
Writing Reaction Mechanisms in Organic Chemistry
TRIMOLECULAR STEPS Trimolecular steps are rare because of the large
decrease in entropy associated with three molecules simultaneously assuming
the proper orientation for reaction. Hint 2. 10 Avoid formulating mechanisms
involving ...
Audrey Miller, Philippa H. Solomon, 2000
7
Encyclopedia of Chemical Physics and Physical Chemistry: ...
A3.4.4. 3 Trimolecular reactions Trimolecular reactions require the simultaneous
encounter of three particles. At the usually low particle densities of gas phase
reactions they are relatively unlikely. Examples for trimolecular reactions are
atom ...
Nicholas D. Spencer, John H. Moore, 2001
8
Cutaneous Medicine: Cutaneous Manifestations of Systemic Disease
A trimolecular complex, comprising the TCR, a peptide fragment of the antigen,
and the class II major histocompatibility complex (MHC) molecule of the antigen-
presenting cell, is required for the generation of an autoimmune response.
Thomas T. Provost, John A. Flynn, 2001
9
Vaccinia Virus and Poxvirology: Methods and Protocols
We have termed this method trimolecular recombination. cDNA libraries of as
many as 107 or more independent viral recombinants can be constructed by
trimolecular recombination. For the first time, large, diverse, and representative
cDNA ...
Substitution of c0/2 for c, and T for fin (12) gives: (13) Similarly, for unimolecular
reactions of the type AB — » products, the rate law v_ = — dc/dt = kc (c = CAB)
yields the equation _ In2 _ 0.693 runimolecular — ~T~ TM 7 • and for trimolecular
...
Egon Wiberg, Nils Wiberg, 2001
