与 «NUCLEOPHILE»相关的英语书籍
在以下的参考文献中发现
nucleophile的用法。与
nucleophile相关的书籍以及同一来源的简短摘要提供其在 英语文献中的使用情境。
In the case of an SN1 reaction, the nucleophile does not become involved until
after the rate-determining step. Therefore, changing the nucleophile has no effect
on the rate of an SN1 reaction, although it may change the product of the reaction
...
2
Organic Chemistry: An Acid—Base Approach
A nucleophile is a species that donates electrons to carbon, as first introduced in
Chapter 2, Section 2.6. A nucleophile is any species that donates electrons to an
electron-deficient car- bon, forming a new bond to carbon. In the previous ...
3
Modern Physical Organic Chemistry
11.5.9 Structure-Function Correlations with the Nucleophile The rates of SN2
reactions correlate well with relative nucleophilicities, because the nucleophile is
intimately involved in the rate-determining step. In SN1 reactions, the nucleophile
...
Eric V. Anslyn, Dennis A. Dougherty, 2006
4
Advanced Organic Chemistry: Part A: Structure and Mechanisms
and nucleophile. 269 RY + rate = - d[RX] dt = )t[RX][Y: Because the nucleophile is
intimately involved in the rate-determining step, not only will the rate depend on
its concentration, but the nature of the nucleophile will be very important in ...
Francis A. Carey, Richard J. Sundberg, 2000
If a nucleophile but no acid or base is present, the reaction mechanism will begin
with the nucleophile attacking the electrophilic carbonyl carbon atom (make a
new bond between a nucleophile and an electrophile). The 11- bond of the ...
William Brown, Brent Iverson, Eric Anslyn, 2013
6
Chemical Structure and Reactivity: An Integrated Approach
In the second stage, the tosylate is reacted with sodium azide, resulting in the
azide nucleophile displacing the tosylate group. Finally, the azide is reduced
using LiAlH4 to give the amine. 11.7.3 The effect of the nucleophile In the SN1 ...
James Keeler, Peter Wothers, 2013
7
Advanced Organic Chemistry: Part A: Structure and Mechanisms
The optimum reactant from a steric point of view is CH3–X, because it provides
the minimum hindrance to approach of the nucleophile. Each replacement of
hydrogen by an alkyl group decreases the rate of reaction. As in the case of the ...
Francis A. Carey, Richard J. Sundberg, 2007
8
CRC Handbook of Organic Photochemistry and Photobiology, ...
Arnold, R.D. and Du, X., The photochemical nucleophile-olefin combination,
aromatic substitution (photo-NOCAS) reaction. Part 5: methanol-monoterpenes (a
- and P-pinene, tricyclene and nopol), 1,4-dicyanobenzene, Can. J. Chem., 72,
403, ...
William M. Horspool, Francesco Lenci, 2003
9
Organic Chemistry, part 2 of 3
In an SN1 reaction, the addition of the nucleophile to the sp3 hybridized carbon
takes place after the leaving group departs. Therefore, the nucleophile has no
effect on the rate of the reaction because the rate of addition of the nucleophile is
...
10
Human Anatomy: Skeletal and Muscular Systems
The line, leading from the right edge of the page to each electrophile and ending
in an arrowhead, represents the attack of some nucleophile upon that
electrophile, with the point of attack being the atom at which the arrowhead is
directed.
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找出国内和国际出版社所讨论的内容，以及词语
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Some respite from Testing times
Which hydrogen atom is replaced by the nucleophile?” What I say is, “Para position.” What I think is, “Which past sin made karma throw me ... «The Hindu, 七月 15»
Dispelling nickel's catalytic demons
The team proposes that the nucleophile attacks the metal–carbon bond directly, similar to that seen in to Pd(iv) and Pt(iv) systems. Figure 3 – A ... «Royal Society of Chemistry, 六月 15»
Chemical doublespeak
... where a focus on the metal's electrophilic attack in a carboalumination reaction — rather than the nucleophile formed by the attack — led to ... «Nature.com, 六月 15»
Alkynes reverse reactivity
... conjugate addition of the nucleophile beta- to iodine (figure 3). Alpha-elimination of 2-iodobenzoic acid to give a carbene and a 1,2-migration ... «Royal Society of Chemistry, 一月 15»
Try Some Reactions. Actually, Try Them All.
... this time varying catalyst loading, amount of nucleophile, and amount of base. 5 of the 6 yielded to that optimization, which confirms the usual ... «Corante, 十一月 14»
Boron and beryllium finally shake hands
10 years ago, few reactions existed where boron behaved as an nucleophile. That all changed with the advent of lithium diazaborolide in 2006 ... «Royal Society of Chemistry, 十一月 14»
The Ebola questions
(NH3 is a stronger nucleophile and a slightly smaller molecule than H2O). http://www.ncbi.nlm.nih.gov/pmc/articles/PMC354068/?page=1 The ... «Nature.com, 十月 14»
Neil Garg's Organic Chemistry: UCLA's Most Beloved Class
Carbocation, yeah you, it's time to bounce / Nucleophile, do your thing, attack, it's time to pounce." In making the video, Butler said, she learned ... «India West, 七月 14»
An Easy Way to Make Cyclic Peptides
The reaction needs a strong nucleophile, like thiolate. O- would work, but then you'd be outside of normal pH ranges. As for para-specific, the ... «Corante, 七月 14»
Rice University produces carbon-capture breakthrough
"You've got to have that nucleophile (the sulfur or nitrogen atoms) to start the polymerization reaction. This would never work on simple ... «EurekAlert, 六月 14»
